Fluctuation Electron Microscopy of Medium-Range Order in Amorphous Silicon

Fluctuation electron microscopy is a transmission electron microscopy technique for studying medium-range order in disordered materials. We compute the variance for the image intensity of low-resolution hollow-cone dark field electron micrographs as a function of the diffracting condition and microscope resolution. The variance is sensitive to fluctuations in diffraction from mesoscopic volumes of the sample. It carries information about medium-range order via the three- and four-body atomic distribution functions. Fluctuation microscopy has been applied to the study of amorphous silicon, with and without alloying with hydrogen. We find that amorphous silicon has significant medium-range order, more than can be described by the conventional continuous random network model. The structure is better described by a paracrystalline model, which consists of strained topologically crystalline grains which may or may not be embedded in a more disordered matrix. Experiments show a continuous evolution of medium-range order in films deposited with increasing substrate temperature from the amorphous to polycrystalline regimes, which is counter to the belief that this structural transition is a discontinuous order-disorder phase transition. In the paracrystalline model, this increase is caused by the topologically crystalline grains growing, or occupying a greater volume fraction, or both. Experiments also show that hydrogenated amorphous silicon deposited by a variety of methods shares the paracrystalline structure. The medium-range order of hydrogenated amorphous silicon is affected by exposure to visible-spectrum white light. Films deposited by different methods have different responses, which may be connected to differences in the creation of metastable electrical defects known as the Staebler-Wronski effect.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Physics

Year dc:date

2012

Author dc:creator

• Voyles, Paul Marriner

• amorphous
• silicon
• microscopy
• diffraction
• paracrystalline
• dark-field
• medium-range order (mro)
• coherence
• semiconductors
• hydrogenated
• applescripts

Statement dc:rights

• Voyles 2001 ©

Language dc:language

en

Handle dc:identifier

http://hdl.handle.net/2142/35205

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/35205