Enzymatic Enhancement of Water Removal In the Dry Grind Corn to Ethanol Process

The removal of water from coproducts in the fuel ethanol process requires a significant energy input. The drying of the coproducts is responsible for as much as 32% of the total utilities cost of the process. In this study, improvements in the energy and water balances of the corn to ethanol process and a decrease in ethanol production costs were achieved. Significant reductions in water-binding capacity of whole stillage were found for two, commercially available, cell wall degrading enzymes, GC220 and MGC. The addition of a protease, GC106, during fermentation was found to significantly enhance ethanol production rates as well as reduce the water binding capacity of the mash. Improvements in fermentation rates were achieved by the addition of GC106 with either GC220 or MGC. To achieve both enhanced dewatering and increased fermentation rates, it was recommended that a plant dose their fermentors using either a MGC/GC106 volume combination of 0.02/0.02 mL or a GC220/GC106 combination of 0.015/0.01 mL. A plant trial was conducted to evaluate the scale-up of enhanced water removal from whole stillage by enzyme addition. Enzymes added during this trial proved to be effective, and an increase in the amount of water being removed during centrifugation was observed during the trial. The firing rate of the drier decreased significantly during enzyme addition, resulting in 12% less natural gas required to produce one gallon of ethanol. DDGS composition was not affected by the enzyme addition. Process simulation results from the enzymatic dewatering model showed a decrease in utility consumption compared to the conventional model. A sensitivity analysis showed a tradeoff between the enzyme cost and the drier's natural gas savings. Because of the non-linear nature of enzyme activity, as the amount of enzyme added was linearly decreased, its resulting effects on the process were non-linear. Even if maximum dewatering effects are not achieved, significant savings in natural gas cost could still be obtained.

Name thesis:degree_name

Doctor of Philosophy (PhD)

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Energy, Environmental and Chemical Engineering

Year dc:date.available

2009

Author dc:creator

• Thomas, Ana Beatriz

Contributors dc:contributor

• Muthanna Al-Dahhan

• Engineering
• Chemical
• Corn
• Enzymes
• Ethanol
• Fermentation
• Hydrolysis
• Water

Language dc:language

English (en)

DOI

https://doi.org/10.7936/K7BV7DPJ

OAI identifier oai:identifier

oai:openscholarship.wustl.edu:etd-1347