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University of Illinois at Urbana-Champaign
Rhenium Carbido Carbonyl Cluster Complexes With Group 12 Metal Centers
Abstract
dc:descriptionExploration of mercury capped rhenium carbido carbonyl clusters as potential labeling agents was initiated. The reaction of [PPh4]2[Re 7C(CO)21HgCl] with L-cysteine in aqueous acetone formed the complex [PPh4]2[Re7C(CO)21HgSCH 2CH(NH3)CO2]. In order to explore further reactions in aqueous solution, work was carried out with [Na]2[Re7C(CO) 21HgCl]. Preliminary work indicates that this complex has potential as an electron dense, easily detectable label for sulfhydryl sites in proteins.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Wright, Chris Aaron
- Contributors dc:contributor
-
- Shapley, John R.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9990193
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84503