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University of Illinois at Urbana-Champaign
Synthesis and Characterization of Alkyl Tetra-, Tri-, and Triskaidecazirconates
Abstract
dc:descriptionThe ambient temperature hydrolysis product of tetra-n-propyl orthozirconate was identified as [Zr3O](OPrn) 10 by 13C NMR spectroscopy and elemental analysis. Ethanolysis of [Zr3O](OPrn) 10 yielded the ethoxy derivative of the trizirconate which was characterized by 13C NMR spectroscopy and elemental analysis. Reaction of the trizirconates with the parent alcohol resulted in the formation of alcohol adducts which are thought to have structures similar to that reported for {[Hf3O](OEt)10(EtOH)}2.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Pafford, Margaret Mary Elizabeth
- Contributors dc:contributor
-
- Klemperer, Walter G.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9990102
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84491