{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84491"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84491","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"Synthesis and Characterization of Alkyl Tetra-, Tri-, and Triskaidecazirconates","abstract":"The ambient temperature hydrolysis product of tetra-n-propyl orthozirconate was identified as [Zr3O](OPrn) 10 by 13C NMR spectroscopy and elemental analysis. Ethanolysis of [Zr3O](OPrn) 10 yielded the ethoxy derivative of the trizirconate which was characterized by 13C NMR spectroscopy and elemental analysis. Reaction of the trizirconates with the parent alcohol resulted in the formation of alcohol adducts which are thought to have structures similar to that reported for {[Hf3O](OEt)10(EtOH)}2.","abstract_html":"The ambient temperature hydrolysis product of tetra-n-propyl orthozirconate was identified as [Zr3O](OPrn) 10 by 13C NMR spectroscopy and elemental analysis. Ethanolysis of [Zr3O](OPrn) 10 yielded the ethoxy derivative of the trizirconate which was characterized by 13C NMR spectroscopy and elemental analysis. Reaction of the trizirconates with the parent alcohol resulted in the formation of alcohol adducts which are thought to have structures similar to that reported for {[Hf3O](OEt)10(EtOH)}2.","abstract_has_math":false,"creators":["Pafford, Margaret Mary Elizabeth"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Klemperer, Walter G."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:14:47Z","date_published":"2015-09-25T22:14:47Z","updated_at":"2026-07-22T22:26:23Z","subjects":["Chemistry, Inorganic"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI9990102"],"render_values":[{"text":"(MiAaPQ)AAI9990102","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84491","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Klemperer, Walter G."]},{"key":"dc:creator","label":"Author","values":["Pafford, Margaret Mary Elizabeth"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:14:47Z","10000-01-01","2000"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Inorganic"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84491","(MiAaPQ)AAI9990102"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The ambient temperature hydrolysis product of tetra-n-propyl orthozirconate was identified as [Zr3O](OPrn) 10 by 13C NMR spectroscopy and elemental analysis. Ethanolysis of [Zr3O](OPrn) 10 yielded the ethoxy derivative of the trizirconate which was characterized by 13C NMR spectroscopy and elemental analysis. Reaction of the trizirconates with the parent alcohol resulted in the formation of alcohol adducts which are thought to have structures similar to that reported for {[Hf3O](OEt)10(EtOH)}2.","Made available in DSpace on 2015-09-25T22:14:47Z (GMT). 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Ethanolysis of [Zr3O](OPrn) 10 yielded the ethoxy derivative of the trizirconate which was characterized by 13C NMR spectroscopy and elemental analysis. Reaction of the trizirconates with the parent alcohol resulted in the formation of alcohol adducts which are thought to have structures similar to that reported for {[Hf3O](OEt)10(EtOH)}2.","Made available in DSpace on 2015-09-25T22:14:47Z (GMT). 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