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University of Illinois at Urbana-Champaign
An Organometallic Approach to Iron Triazacyclononane Coordination Complexes
Abstract
dc:descriptionThe active site of NiFe hydrogenase features a bis(thiolate) bridged nickel-iron site, where the iron is bound to two carbonyls and a cyanide. The reaction of the square planar Ni(N2S2), where (N2S2)2- = -SCH2CH2N(Me)CH2CH 2N(Me)CH2CH2S- and (Me 3TACN)FeCl2 gives [Ni(N2S2)FeCl(Me3TACN)](BPh 4), a complex with a bis(thiolate) bridge between nickel and iron. The reactivity of this complex with CN- and CO was explored.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Moreland, Andrew Colby
- Contributors dc:contributor
-
- Rauchfuss, Thomas B.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9990088
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84489