{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84489"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84489","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"An Organometallic Approach to Iron Triazacyclononane Coordination Complexes","abstract":"The active site of NiFe hydrogenase features a bis(thiolate) bridged nickel-iron site, where the iron is bound to two carbonyls and a cyanide. The reaction of the square planar Ni(N2S2), where (N2S2)2- = -SCH2CH2N(Me)CH2CH 2N(Me)CH2CH2S- and (Me 3TACN)FeCl2 gives [Ni(N2S2)FeCl(Me3TACN)](BPh 4), a complex with a bis(thiolate) bridge between nickel and iron. The reactivity of this complex with CN- and CO was explored.","abstract_html":"The active site of NiFe hydrogenase features a bis(thiolate) bridged nickel-iron site, where the iron is bound to two carbonyls and a cyanide. The reaction of the square planar Ni(N2S2), where (N2S2)2- = -SCH2CH2N(Me)CH2CH 2N(Me)CH2CH2S- and (Me 3TACN)FeCl2 gives [Ni(N2S2)FeCl(Me3TACN)](BPh 4), a complex with a bis(thiolate) bridge between nickel and iron. The reactivity of this complex with CN- and CO was explored.","abstract_has_math":false,"creators":["Moreland, Andrew Colby"],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Rauchfuss, Thomas B."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:14:47Z","date_published":"2015-09-25T22:14:47Z","updated_at":"2026-07-22T22:26:23Z","subjects":["Chemistry, Inorganic"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI9990088"],"render_values":[{"text":"(MiAaPQ)AAI9990088","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84489","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Rauchfuss, Thomas B."]},{"key":"dc:creator","label":"Author","values":["Moreland, Andrew Colby"]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:14:47Z","10000-01-01","2000"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Inorganic"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84489","(MiAaPQ)AAI9990088"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The active site of NiFe hydrogenase features a bis(thiolate) bridged nickel-iron site, where the iron is bound to two carbonyls and a cyanide. The reaction of the square planar Ni(N2S2), where (N2S2)2- = -SCH2CH2N(Me)CH2CH 2N(Me)CH2CH2S- and (Me 3TACN)FeCl2 gives [Ni(N2S2)FeCl(Me3TACN)](BPh 4), a complex with a bis(thiolate) bridge between nickel and iron. The reactivity of this complex with CN- and CO was explored.","Made available in DSpace on 2015-09-25T22:14:47Z (GMT). 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The reaction of the square planar Ni(N2S2), where (N2S2)2- = -SCH2CH2N(Me)CH2CH 2N(Me)CH2CH2S- and (Me 3TACN)FeCl2 gives [Ni(N2S2)FeCl(Me3TACN)](BPh 4), a complex with a bis(thiolate) bridge between nickel and iron. The reactivity of this complex with CN- and CO was explored.","Made available in DSpace on 2015-09-25T22:14:47Z (GMT). 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