The Reactivity of Tetrathioperrhenate

The reaction of ReS4- with nitriles in the presence of S8 yielded azadithiolene (S2NCR 2-) complexes, ReS(S4)(S2NCR)- (R = C6H5, 4-C6H4CF 4, 4-C6H4CO2Me, or 4-C6H 4NO2). The reaction of ReS4- with CF3CN in the presence of 1/8 equiv of S8 yielded ReS(S2NCCF3)2-, in the presence of Me3NO this reaction yielded cis and trans isomers of ReO(S2NCCF3)2-. The trifluoroacetonitrile adduct cis-ReO(S2NCCF 3)2- was crystallographically characterized.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2015

Author dc:creator

• Goodman, Jonathan T.

Contributors dc:contributor

• Rauchfuss, Thomas B.

• Chemistry, Inorganic

Language dc:language

eng

Identifier

(MiAaPQ)AAI9944864

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/84444