{"id":{"repo_id":"uiuc","oai_identifier":"oai:www.ideals.illinois.edu:2142/84444"},"canonical_url":"https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/84444","repository":{"repo_id":"uiuc","name":"University of Illinois - Urbana-Champaign","base_url":"https://www.ideals.illinois.edu/oai-pmh"},"display":{"title":"The Reactivity of Tetrathioperrhenate","abstract":"The reaction of ReS4- with nitriles in the presence of S8 yielded azadithiolene (S2NCR 2-) complexes, ReS(S4)(S2NCR)- (R = C6H5, 4-C6H4CF 4, 4-C6H4CO2Me, or 4-C6H 4NO2). The reaction of ReS4- with CF3CN in the presence of 1/8 equiv of S8 yielded ReS(S2NCCF3)2-, in the presence of Me3NO this reaction yielded cis and trans isomers of ReO(S2NCCF3)2-. The trifluoroacetonitrile adduct cis-ReO(S2NCCF 3)2- was crystallographically characterized.","abstract_html":"The reaction of ReS4- with nitriles in the presence of S8 yielded azadithiolene (S2NCR 2-) complexes, ReS(S4)(S2NCR)- (R = C6H5, 4-C6H4CF 4, 4-C6H4CO2Me, or 4-C6H 4NO2). The reaction of ReS4- with CF3CN in the presence of 1/8 equiv of S8 yielded ReS(S2NCCF3)2-, in the presence of Me3NO this reaction yielded cis and trans isomers of ReO(S2NCCF3)2-. The trifluoroacetonitrile adduct cis-ReO(S2NCCF 3)2- was crystallographically characterized.","abstract_has_math":false,"creators":["Goodman, Jonathan T."],"institution":"University of Illinois at Urbana-Champaign","degree_name":"Ph.D.","degree_level":"Dissertation","degree_discipline":"Chemistry","degree_department":null,"school":null,"contributors":["Rauchfuss, Thomas B."],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2015,"date_issued":"2015-09-25T22:14:32Z","date_published":"2015-09-25T22:14:32Z","updated_at":"2026-07-22T22:26:23Z","subjects":["Chemistry, Inorganic"],"languages":["eng"],"rights":[],"rights_urls":[],"identifier_entries":[{"key":"dc:identifier","label":"Identifier","values":["(MiAaPQ)AAI9944864"],"render_values":[{"text":"(MiAaPQ)AAI9944864","href":null,"code":true}]}]},"links":{"outbound_url":"http://hdl.handle.net/2142/84444","outbound_label":"Handle","outbound_source":"dc:identifier"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor","label":"Contributor","values":["Rauchfuss, Thomas B."]},{"key":"dc:creator","label":"Author","values":["Goodman, Jonathan T."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date","label":"Dc Date","values":["2015-09-25T22:14:32Z","10000-01-01","1999"]},{"key":"dc:type","label":"Dc Type","values":["text"]},{"key":"thesis:degree_discipline","label":"Discipline","values":["Chemistry"]},{"key":"thesis:degree_level","label":"Degree Level","values":["Dissertation"]},{"key":"thesis:degree_name","label":"Degree Name","values":["Ph.D."]},{"key":"thesis:institution_name","label":"Thesis Institution Name","values":["University of Illinois at Urbana-Champaign"]}]},{"id":"subjects_keywords","label":"Subjects and Keywords","entries":[{"key":"dc:subject","label":"Dc Subject","values":["Chemistry, Inorganic"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language","label":"Dc Language","values":["eng"]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier","label":"Identifier","values":["http://hdl.handle.net/2142/84444","(MiAaPQ)AAI9944864"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description","label":"Description","values":["The reaction of ReS4- with nitriles in the presence of S8 yielded azadithiolene (S2NCR 2-) complexes, ReS(S4)(S2NCR)- (R = C6H5, 4-C6H4CF 4, 4-C6H4CO2Me, or 4-C6H 4NO2). The reaction of ReS4- with CF3CN in the presence of 1/8 equiv of S8 yielded ReS(S2NCCF3)2-, in the presence of Me3NO this reaction yielded cis and trans isomers of ReO(S2NCCF3)2-. The trifluoroacetonitrile adduct cis-ReO(S2NCCF 3)2- was crystallographically characterized.","Made available in DSpace on 2015-09-25T22:14:32Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9944864.pdf: 4005774 bytes, checksum: 9e9ee72403e285eb536a813b12bb0d4f (MD5) Previous issue date: 1999","Embargo set by: Seth Robbins for item 85725 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","146 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1999."]},{"key":"dc:title","label":"Title","values":["The Reactivity of Tetrathioperrhenate"]}]}],"canonical_facts":{"dc:contributor":["Rauchfuss, Thomas B."],"dc:creator":["Goodman, Jonathan T."],"dc:date":["2015-09-25T22:14:32Z","10000-01-01","1999"],"dc:description":["The reaction of ReS4- with nitriles in the presence of S8 yielded azadithiolene (S2NCR 2-) complexes, ReS(S4)(S2NCR)- (R = C6H5, 4-C6H4CF 4, 4-C6H4CO2Me, or 4-C6H 4NO2). The reaction of ReS4- with CF3CN in the presence of 1/8 equiv of S8 yielded ReS(S2NCCF3)2-, in the presence of Me3NO this reaction yielded cis and trans isomers of ReO(S2NCCF3)2-. The trifluoroacetonitrile adduct cis-ReO(S2NCCF 3)2- was crystallographically characterized.","Made available in DSpace on 2015-09-25T22:14:32Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9944864.pdf: 4005774 bytes, checksum: 9e9ee72403e285eb536a813b12bb0d4f (MD5) Previous issue date: 1999","Embargo set by: Seth Robbins for item 85725 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs","U of I Only","146 p.","Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1999."],"dc:identifier":["http://hdl.handle.net/2142/84444","(MiAaPQ)AAI9944864"],"dc:language":["eng"],"dc:subject":["Chemistry, Inorganic"],"dc:title":["The Reactivity of Tetrathioperrhenate"],"dc:type":["text"],"thesis:degree_discipline":["Chemistry"],"thesis:degree_level":["Dissertation"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Illinois at Urbana-Champaign"]},"updated_at":"2026-07-22T22:26:23Z"}