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University of Illinois at Urbana-Champaign
Pentamethylcyclopentadienyl Osmium Chemistry: An Approach to Transition Metal Alkane Complexes
Abstract
dc:descriptionProtonation of $\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me$ with $\rm HBF\sb4{\cdot}Et\sb2O$ at room temperature affords the Os$\sp{\rm IV}$ alkyl hydride complex $\lbrack\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me(H)\rbrack\lbrack BF\sb4\rbrack.$ Protonation of $\rm(C\sb5Me\sb5)Os(dmpm)Me$ at ${-}120\sp\circ$C with H2C(SO2CF3)2 in CDFC12 generates the cis methyl/hydride compound $\lbrack\rm(C\sb5Me\sb5)Os(dmpm)Me(H)\sp+\rbrack.$.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Gross, Christopher L.
- Contributors dc:contributor
-
- Girolami, G.S.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9812601
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84377