Pentamethylcyclopentadienyl Osmium Chemistry: An Approach to Transition Metal Alkane Complexes
type: CreativeWork
description: Protonation of $\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me$ with $\rm HBF\sb4{\cdot}Et\sb2O$ at room temperature affords the Os$\sp{\rm IV}$ alkyl hydride complex $\lbrack\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me(H)\rbrack\lbrack BF\sb4\rbrack.$ Protonation of $\rm(C\sb5Me\sb5)Os(dmpm)Me$ at ${-}120\sp\circ$C with H2C(SO2CF3)2 in CDFC12 generates the cis methyl/hydride compound $\lbrack\rm(C\sb5Me\sb5)Os(dmpm)Me(H)\sp+\rbrack.$.
abstract: Protonation of $\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me$ with $\rm HBF\sb4{\cdot}Et\sb2O$ at room temperature affords the Os$\sp{\rm IV}$ alkyl hydride complex $\lbrack\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me(H)\rbrack\lbrack BF\sb4\rbrack.$ Protonation of $\rm(C\sb5Me\sb5)Os(dmpm)Me$ at ${-}120\sp\circ$C with H2C(SO2CF3)2 in CDFC12 generates the cis methyl/hydride compound $\lbrack\rm(C\sb5Me\sb5)Os(dmpm)Me(H)\sp+\rbrack.$.
author: Gross, Christopher L.
language: eng
keywords: Chemistry, Inorganic
date published: 2015-09-25T22:14:12Z
date modified: 2026-07-22T22:26:23Z
provider: University of Illinois - Urbana-Champaign
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Illinois at Urbana-Champaign

PropertyValue
property ID: Handle
value: http://hdl.handle.net/2142/84377