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University of Illinois at Urbana-Champaign
Palladium-Catalyzed Alkenylsilanol Cross -Coupling Reactions: Method Development and Mechanistic Analysis
Abstract
dc:descriptionThe transmetalation mechanism was examined through the natural abundance 13C NMR kinetic isotope effect (KIE) studies. This provided evidence for either palladium-olefin complexation or a Heck-type carbometalation as the turnover-limiting step for these cross-coupling reactions.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Sweis, Ramzi Farah
- Contributors dc:contributor
-
- Denmark, Scott E.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI3131032
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84140