Using Covalent and Non-Covalent Chemistry to Control Properties of Single -Walled Carbon Nanotubes

Electrophoretic mobility control is demonstrated via covalent functionalization with 4-hydroxybenzene diazonium and non-covalent functionalization with sodium cholate surfactant. Solution-phase solubility without surfactants can be achieved using high levels of covalent functionalization with aryl hydroxyl or aryl carboxylic acid moieties. Polymer theory based models for the Hildebrand and Hansen solubility parameters confirm the effect of functionalization. The adsorption of SWNT to silicon oxide surfaces modified with 3-aminopropyltriethoxysilane (APTES) is controlled via type of functional moiety, extent of functionalization, and nature of silicon oxide surface chemistry. Self-consistent field theory for polymer systems is applied and describes the effect of functionalization on SWNT adsorption thermodynamics.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemical Engineering

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2015

Author dc:creator

• Usrey, Monica

Contributors dc:contributor

• Michael S. Strano

• Engineering, Chemical

Language dc:language

eng

Identifier

(MiAaPQ)AAI3347549

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/82418