Covalent Attachment of Coordinatively-Saturated Metal Complexes to Horse Cytochrome-C Lysines

The coordinatively saturated complexes $\rm Ru\sp{II}(NH\sb3)\sb5INH\sp{2+}$ (INH = isonicotinic acid) and $\rm Ru\sp{II}bp\sb2cmbpH\sp{2+}$ (bp = 2,2$\sp\prime$-bipyridine, cmbp = 4$\sp\prime$-methyl-2,2$\sp\prime$-bipyridine-4-carboxylic acid) have been covalently attached to horse cytochrome c via a carbodiimide-promoted condensation of the pendant carboxylate of the complexes with the $\varepsilon$-amine of lysine to form an amide-bond linkage.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2014

Author dc:creator

• Wallin, Sten Andreas

Contributors dc:contributor

• Scott, R.A.

• Chemistry, Biochemistry
• Chemistry, Inorganic

Identifier

(UMI)AAI8815436

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/70403