Spectroscopic Studies of Rhodium(ii) Perfluorobutyrate and Synthesis of Metallo-Hapten Complexes

In part I, the bonding interactions between rhodium(II) perfluorobutyrate (Rh(,2)(pfb)(,4)) and several Lewis bases was investigated using electron paramagnetic resonance (EPR) and infrared (IR) spectroscopy. The shift of the g-value in the EPR spectra of the spin label complex 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) and the shift of the infrared stretching frequency of carbon monoxide (CO) were measured as various Lewis bases bound to the second rhodium center.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2014

Author dc:creator

• Stahlbush, James Richard

• Chemistry, Inorganic

Identifier

(UMI)AAI8623419

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/70333