Spectroscopic Studies of Rhodium(ii) Perfluorobutyrate and Synthesis of Metallo-Hapten Complexes
type: CreativeWork
description: In part I, the bonding interactions between rhodium(II) perfluorobutyrate (Rh(,2)(pfb)(,4)) and several Lewis bases was investigated using electron paramagnetic resonance (EPR) and infrared (IR) spectroscopy. The shift of the g-value in the EPR spectra of the spin label complex 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) and the shift of the infrared stretching frequency of carbon monoxide (CO) were measured as various Lewis bases bound to the second rhodium center.
abstract: In part I, the bonding interactions between rhodium(II) perfluorobutyrate (Rh(,2)(pfb)(,4)) and several Lewis bases was investigated using electron paramagnetic resonance (EPR) and infrared (IR) spectroscopy. The shift of the g-value in the EPR spectra of the spin label complex 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) and the shift of the infrared stretching frequency of carbon monoxide (CO) were measured as various Lewis bases bound to the second rhodium center.
author: Stahlbush, James Richard
keywords: Chemistry, Inorganic
date published: 2014-12-15T23:18:43Z
date modified: 2026-07-22T22:26:02Z
provider: University of Illinois - Urbana-Champaign
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Illinois at Urbana-Champaign

PropertyValue
property ID: Handle
value: http://hdl.handle.net/2142/70333