Spectroscopic Studies of Rhodium(ii) Perfluorobutyrate and Synthesis of Metallo-Hapten Complexes
In part I, the bonding interactions between rhodium(II) perfluorobutyrate (Rh(,2)(pfb)(,4)) and several Lewis bases was investigated using electron paramagnetic resonance (EPR) and infrared (IR) spectroscopy. The shift of the g-value in the EPR spectra of the spin label complex 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) and the shift of the infrared stretching frequency of carbon monoxide (CO) were measured as various Lewis bases bound to the second rhodium center.
University of Illinois - Urbana-Champaign
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University of Illinois at Urbana-Champaign