Back to results
University of Illinois at Urbana-Champaign
Part One: Catalytic Reactions of Anion-Exchange Resin Bound Dodecarhodium Triacontacarbonyl Dianion and Its Derivatives and Part Two: Properties and Reactions of Neutral Non-Polar Solvent Soluble Binuclear Complexes
Abstract
dc:descriptionThe resin support was the Dowes 1-X8 anion exchange resin in the chloride form. Exchange of the cluster at room temperature under an inert atmosphere leads to intact Rh(,12) (CO)(,30)('2-) being bound. This material exhibits only limited activity for the hydroformylation of of 1-hexene, accompanied by extensive isomerization of the substrate to 2-hexene, at 100 C and 8 atm of H(,2)/CO.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2014
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Desmond, Michael Joseph
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (UMI)AAI8108484
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/67239