https://search.dev.ndltd.org/etd/uiuc/oai:www.ideals.illinois.edu:2142/67239
type: CreativeWork
name: Part One: Catalytic Reactions of Anion-Exchange Resin Bound Dodecarhodium Triacontacarbonyl Dianion and Its Derivatives and Part Two: Properties and Reactions of Neutral Non-Polar Solvent Soluble Binuclear Complexes
description: The resin support was the Dowes 1-X8 anion exchange resin in the chloride form. Exchange of the cluster at room temperature under an inert atmosphere leads to intact Rh(,12) (CO)(,30)('2-) being bound. This material exhibits only limited activity for the hydroformylation of of 1-hexene, accompanied by extensive isomerization of the substrate to 2-hexene, at 100 C and 8 atm of H(,2)/CO.
abstract: The resin support was the Dowes 1-X8 anion exchange resin in the chloride form. Exchange of the cluster at room temperature under an inert atmosphere leads to intact Rh(,12) (CO)(,30)('2-) being bound. This material exhibits only limited activity for the hydroformylation of of 1-hexene, accompanied by extensive isomerization of the substrate to 2-hexene, at 100 C and 8 atm of H(,2)/CO.
author: Desmond, Michael Joseph
language: eng
keywords: Chemistry, Inorganic
date published: 2014-12-13T20:11:01Z
date modified: 2026-07-22T22:25:57Z
provider: University of Illinois - Urbana-Champaign
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Illinois at Urbana-Champaign

PropertyValue
property ID: Handle
value: http://hdl.handle.net/2142/67239