Part One: Catalytic Reactions of Anion-Exchange Resin Bound Dodecarhodium Triacontacarbonyl Dianion and Its Derivatives and Part Two: Properties and Reactions of Neutral Non-Polar Solvent Soluble Binuclear Complexes
The resin support was the Dowes 1-X8 anion exchange resin in the chloride form. Exchange of the cluster at room temperature under an inert atmosphere leads to intact Rh(,12) (CO)(,30)('2-) being bound. This material exhibits only limited activity for the hydroformylation of of 1-hexene, accompanied by extensive isomerization of the substrate to 2-hexene, at 100 C and 8 atm of H(,2)/CO.
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