How water meets a hydrophobic surface: reluctantly and with fluctuations

By definition hydrophobic substances hate water. Water placed on a hydrophobic surface will form a drop in order to minimize its contact area. What happens when water is forced into contact with a hydrophobic surface? One theory is that an ultra-thin low-density region forms near the surface. This depleted region would have implications in such diverse areas as colloidal self-assembly, and the boundary conditions of fluid flow. However, the literature still remains divided as to whether or not such a depleted region exists. To investigate the existence of this layer, we have employed three surfacesensitive techniques, time-resolved phase-modulated ellipsometry, surface plasmon resonance, and X-ray reflectivity. Both ellipsometry and X-ray reflectivity provide strong evidence for the low-density layer and illuminate unexpected temporal behavior. Using all three techniques, we found surprising fluctuations at the interface with a non-Gaussian distribution and a single characteristic time on the order of tenths of seconds. This information supports the idea that the boundary fluctuates with something akin to capillary waves. We have also investigated the dependence of the static and dynamic properties of the hydrophobic/water interface on variables such as temperature, contact angle, pH, dissolved gasses, and sample quality, among others, in a hope to discover the root of the controversy in the literature. We found that the depletion layer is highly dependent on temperature, contact angle and sample quality. This dependence might explain some of the discrepancies in the literature as different groups often use hydrophobic surfaces with different properties.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Physics

Year dc:date

2012

Author dc:creator

• Poynor Torigoe, Adele Nichole

Contributors dc:contributor

• Granick, Steve

• Water/Hydrophobic Interface
• X-Ray Reflectivity
• Surface Plasmon Resonance

Statement dc:rights

• ©2006 Adele Nichole Poyner Torigoe

Language dc:language

en

Identifier

5641604

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/34836