Asymmetric Lewis base catalysis: I. Lewis base catalyzed halogenation and development of an enantioselective bromocycloetherification reaction; II. enantioselective addition of silyl ketene imines to carbonyl electrophiles

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Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2012

Author dc:creator

• Burk, Matthew

Contributors dc:contributor

• Denmark, Scott E.
• White, Maria C.
• van der Donk, Wilfred A.
• Rauchfuss, Thomas B.

• enantioselective
• Halogenation
• chlorination
• bromination
• iodination
• chlorolactonization
• chloroetherification
• chlorocyloetherification
• bromolactonization
• bromoetherification
• bromocycloetherification
• iodolactonization
• iodoetherification
• iodocycloetherification
• halonium
• haliranium
• bromonium
• bromiranium
• chloronium
• chloriranium
• solvolysis
• racemization
• olefin-to-olefin transfer
• Lewis base
• chiral
• chiral Lewis base
• Lewis base catalysis
• Silicon tetrachloride
• silyl ketene imine
• aldol
• germanium
• crossed aldol
• kinetics
• chiral Bronsted acid

Statement dc:rights

• Copyright 2012 Matthew Burk

Language dc:language

en

Handle dc:identifier

http://hdl.handle.net/2142/34528

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/34528