Asymmetric Lewis base catalysis: I. Lewis base catalyzed halogenation and development of an enantioselective bromocycloetherification reaction; II. enantioselective addition of silyl ketene imines to carbonyl electrophiles
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enantioselective, Halogenation, chlorination, bromination, iodination, chlorolactonization, chloroetherification, chlorocyloetherification, bromolactonization, bromoetherification, bromocycloetherification, iodolactonization, iodoetherification, iodocycloetherification, halonium, haliranium, bromonium, bromiranium, chloronium, chloriranium, solvolysis, racemization, olefin-to-olefin transfer, Lewis base, chiral, chiral Lewis base, Lewis base catalysis, Silicon tetrachloride, silyl ketene imine, aldol, germanium, crossed aldol, kinetics, chiral Bronsted acid
University of Illinois - Urbana-Champaign
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University of Illinois at Urbana-Champaign