Resonant Raman scattering studies of III-V semiconductor microstructures

"Raman spectroscopy, an inelastic light scattering technique, explores III-V semiconductors by conveying crystal lattice structural information and by probing carrier dynamics both directly and via the electron-phonon interaction. We have examined three physical systems accentuating three aspects of Raman utility. AlxGa 1_xAs alloy work emphasizes electronic behavior, migration enhanced epitaxy (MEE) studies highlight structural results, and a phonon-assisted lasing project underscores electron-phonon interaction. The disorder-induced frequency difference between the dipoleforbidden and dipole-allowed longitudinal optic (LO) modes in AlxGa 1_xA s alloys has been investigated as a function of laser photon energy, aluminum mole fraction x, and the indirect versus direct nature of the electronic band gap. For the indirect gap alloy, the intermediate resonant state is an X-valley electron effectively localized because of its short inelastic lifetime. Raman scattering via this state is described by a calculation of the Raman susceptibility that considers the random alloy potential generated by local concentration fluctuations. MEE is a new growth technology that can order these materials in two spatial directions. In a GaSh/ AlSb system we show Raman evidence of this ordering via observation of zone folded acoustic modes and compare to -""-··---·-··- AlAs/GaAs results. In other work resonant Raman documents the effects on the dipole-forbidden interface mode of a periodic corrugation introduced in AlAs barrier GaAs single quantum wells. Finally, we investigate ""phonon-assisted"" lasing in photopumped quantum well heterostructure lasers. Resonant Raman is the natural choice to probe this system purported to have an enhanced electronphonon interaction. For both the AlGaAs/GaAs and AlGaAs/GaAs/lnGaAs structures examined, we provide evidence that indicates first order ""phonon-assisted"" lasing is actually renormalized band gap luminescence filtered by absorption from the unpumped sample volume. Although unable to examine second order ""phonon-assisted"" lasing, we suggest that it is a stimulated Raman process."

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Physics

Year dc:date

2011

Author dc:creator

• Delaney, Malcolm Emil

Contributors dc:contributor

• Klein, Miles V.

• Raman spectroscopy
• semiconductor microstructures
• crystal lattice structure
• carrier dynamics
• electron-phonon interaction

Statement dc:rights

• 1991 Malcolm Emil Delaney

Language dc:language

en

Identifier

3476377

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/23875