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University of Illinois at Urbana-Champaign
Rearrangements and biogenetic relationships of silphinane sesquiterpenes
Abstract
dc:descriptionAcid-catalyzed rearrangement of presilphiperfolanol to silphiperfol-6-ene and α-terrecyclene formed by way of a silphinyl ion intermediate, suggests that the presilphiperfolanyl carbocation could be an important intermediate and a branch point in the biogenesis of triquinane sesquiterpenes such as silphiperfol-6-ene, silphinene, and related compounds.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry, Organic
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2011
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Ho, Jonathan Zhanqi
- Contributors dc:contributor
-
- Coates, Robert M.
Subjects
dc:subject × 1Rights
dc:rights- Statement dc:rights
-
- Copyright 1996 Ho, Jonathan Zhanqi
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
-
9780591198966
AAI9712306
(UMI)AAI9712306 - OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/23622