Rearrangements and biogenetic relationships of silphinane sesquiterpenes
type: CreativeWork
description: Acid-catalyzed rearrangement of presilphiperfolanol to silphiperfol-6-ene and $\alpha$-terrecyclene formed by way of a silphinyl ion intermediate, suggests that the presilphiperfolanyl carbocation could be an important intermediate and a branch point in the biogenesis of triquinane sesquiterpenes such as silphiperfol-6-ene, silphinene, and related compounds.
abstract: Acid-catalyzed rearrangement of presilphiperfolanol to silphiperfol-6-ene and $\alpha$-terrecyclene formed by way of a silphinyl ion intermediate, suggests that the presilphiperfolanyl carbocation could be an important intermediate and a branch point in the biogenesis of triquinane sesquiterpenes such as silphiperfol-6-ene, silphinene, and related compounds.
author: Ho, Jonathan Zhanqi
language: eng
keywords: Chemistry, Organic
date published: 2011-05-07T14:20:57Z
date modified: 2026-07-22T22:25:22Z
provider: University of Illinois - Urbana-Champaign
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: University of Illinois at Urbana-Champaign

PropertyValue
property ID: Handle
value: http://hdl.handle.net/2142/23622