Design, synthesis, and evaluation of selectors and stationary phases for improved liquid chromatographic separations

Finally, the rational design of an improved selector and stationary phase for the carbon cluster buckminsterfullerene (C$\sb{60}$) is described. A tripodal selector containing three π-acidic aromatic rings for simultaneous multipoint interaction with the spherical analyte molecule was immobilized on silica to afford a stationary phase displaying a high degree of retention for buckminsterfullerene, and a large separation factor for separation of the C$\sb{60}$/C$\sb{70}$ mixture.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Welch, Christopher J.

Contributors dc:contributor

• Pirkle, William H.

• Chemistry, Analytical

Statement dc:rights

• Copyright 1992 Welch, Christopher J.

Language dc:language

eng

Identifier

AAI9236621
(UMI)AAI9236621

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/21787