Hydrogen bond mediated self-assembly: Solid state structures and synthesis of building blocks

"The X-ray structure of a trimesic acid$\bullet$pyrene$\bullet$ethanol cocrystal is described. The ""chicken-wire"" network found in trimesic acid was expanded through ethanol bridging of some of the hydrogen bonded carboxylic acid dimers. The expanded chicken wire networks of the structure do not interpenetrate. The Cambridge Crystallographic Data File (CCDF) was searched to determine the ratio of hydroxy bridge carboxylic acids to standard dimers. Standard dimers represented 93%, singly bridged dimers 1%, and doubly bridged dimers 6% of the total number of hits."

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2011

Author dc:creator

• Fenlon, Edward Emmett

Contributors dc:contributor

• Zimmerman, Steven C.

• Chemistry, Organic
• Chemistry, Physical

Statement dc:rights

• Copyright 1995 Fenlon, Edward Emmett

Language dc:language

eng

Identifier

AAI9624344
(UMI)AAI9624344

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/21003