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Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης (ΑΠΘ)
ΜΕΛΕΤΗ ΑΝΤΙΔΡΑΣΕΩΝ ΕΤΕΡΟΚΥΚΛΙΚΩΝ ΑΡΩΜΑΤΙΚΩΝ ΝΙΤΡΩΔΑΜΙΝΩΝ
Abstract
dc:descriptionTHE NITROSATION OF 4-METHYLAMINO-1-METHYL-PYRIDINIUM PERCHLORATE IN 0.1-4.0 N PERCHLORIC ACID IS OF FIRST ORDER IN AMINE AND NITROUS ACID AND FOLLOWS THE RATEEXPRESSION: R=K3 [AMINE] [NITROUS ACID] HO. (I) THE RESPECTIVE NITROSAMINE FORMED IS EASILY DENITROSATED UNDER THE EXPERIMENTAL CONDITIONS. THE VALUE OF K3 IS COMPATIBLE TO THAT OF THE NITROSATION OF 4-METHYLAMINO- PYRIDINE. AN EXAMINATION OF THE K3 VALUES FOR SOME AMINES INDICATES THAT THE NITROSATING AGENT, WHICH IS THE NITROUS ACIDIUM ION, INTERACTS FIRST WITH THE HETEROCYCLIC NUCLEUS. (SHORTENED)
Degree
thesis:*- Grantor dc:publisher
- Αριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης (ΑΠΘ)
- Year dc:date
- 1987
Author and committee
dc:creator, dc:contributor.*- Authors dc:creator
-
- Kiriazis, Leonidas
- Κυριαζής, Λεωνίδας
Subjects
dc:subject × 21- CARBOALKOXY ACETAMIDES
- CARBOMATES
- DIHYDROPYRIDINES
- FREE ENERGY AT ACTIVATION
- MALONATES
- MALONIC ACID - ESTERS
- NITROSATION
- NMR C13
- NMR H1
- PYRIDINES
- ΔΙΥΔΡΟΠΥΡΙΔΙΝΕΣ
- ΕΛΕΥΘΕΡΗ ΕΝΕΡΓΕΙΑ ΕΝΕΡΓΟΠΟΙΗΣΕΩΣ
- ΚΑΡΒΑΜΙΔΙΚΟΙ ΕΣΤΕΡΕΣ
- ΚΑΡΒΟΑΛΚΟΞΗ ΑΚΕΤΑΜΙΔΙΑ
- ΜΗΛΟΝΙΚΟΙ ΕΣΤΕΡΕΣ
- ΝΙΤΡΩΔΩΣΗ
- Πυριδίνες
- Φυσικές Επιστήμες
- Natural Sciences
- Χημεία
- Chemical Sciences
Rights
- Language dc:language
- gre
Identifiers
dc:identifier.*- Identifier
- 10.12681/eadd/0620
- OAI identifier oai:identifier
- oai:10442/0620