The Reactions of Diethyl Bromo- and Chloromalonates with Phenoxide and Ethoxide Ions

In 1940, Niederi and Roth reported that both the diethyl monophenoxy- and diphenoxymalonates were formed in the reaction of diethyl bromomalonate with sodium phenoxide. The reaction has been investigated in an attempt to establish its mechanism. The purpose of this study was to (1) further examine the reaction of diethyl bromomalonate and sodium phenoxide, (2) investigate the behavior of the bromo- ester toward ethoxide ion, and (3) study the reactions of diethyl chloromalonate with phenoxide and ethoxide ions.

Grantor dc:publisher

Creighton University

Year dc:date.issued

1968

Author dc:creator

• Pulickal, Marietta C.H.F.

Advisor dc:contributor.advisor

• Takemura, Kaz H.

Statement dc:rights

• A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above.

Language dc:language.iso

en_US

Handle dc:identifier.uri

http://hdl.handle.net/10504/111775

OAI identifier oai:identifier

oai:cdr.creighton.edu:10504/111775