The Reactions of Diethyl Bromo- and Chloromalonates with Phenoxide and Ethoxide Ions
type: CreativeWork
description: In 1940, Niederi and Roth reported that both the diethyl monophenoxy- and diphenoxymalonates were formed in the reaction of diethyl bromomalonate with sodium phenoxide. The reaction has been investigated in an attempt to establish its mechanism. The purpose of this study was to (1) further examine the reaction of diethyl bromomalonate and sodium phenoxide, (2) investigate the behavior of the bromo- ester toward ethoxide ion, and (3) study the reactions of diethyl chloromalonate with phenoxide and ethoxide ions.
abstract: In 1940, Niederi and Roth reported that both the diethyl monophenoxy- and diphenoxymalonates were formed in the reaction of diethyl bromomalonate with sodium phenoxide. The reaction has been investigated in an attempt to establish its mechanism. The purpose of this study was to (1) further examine the reaction of diethyl bromomalonate and sodium phenoxide, (2) investigate the behavior of the bromo- ester toward ethoxide ion, and (3) study the reactions of diethyl chloromalonate with phenoxide and ethoxide ions.
author: Pulickal, Marietta C.H.F.
language: en_US
date published: 1968
date modified: 2026-07-24T01:52:13Z
provider: Creighton University
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: Creighton University

PropertyValue
property ID: Handle
value: http://hdl.handle.net/10504/111775