{"id":{"repo_id":"creighton","oai_identifier":"oai:cdr.creighton.edu:10504/111775"},"canonical_url":"https://search.dev.ndltd.org/etd/creighton/oai:cdr.creighton.edu:10504/111775","repository":{"repo_id":"creighton","name":"Creighton University","base_url":"https://cdr.creighton.edu/server/oai/request"},"display":{"title":"The Reactions of Diethyl Bromo- and Chloromalonates with Phenoxide and Ethoxide Ions","abstract":"In 1940, Niederi and Roth reported that both the diethyl monophenoxy- and diphenoxymalonates were formed in the reaction of diethyl bromomalonate with sodium phenoxide. The reaction has been investigated in an attempt to establish its mechanism. The purpose of this study was to (1) further examine the reaction of diethyl bromomalonate and sodium phenoxide, (2) investigate the behavior of the bromo- ester toward ethoxide ion, and (3) study the reactions of diethyl chloromalonate with phenoxide and ethoxide ions.","abstract_html":"In 1940, Niederi and Roth reported that both the diethyl monophenoxy- and diphenoxymalonates were formed in the reaction of diethyl bromomalonate with sodium phenoxide. The reaction has been investigated in an attempt to establish its mechanism. The purpose of this study was to (1) further examine the reaction of diethyl bromomalonate and sodium phenoxide, (2) investigate the behavior of the bromo- ester toward ethoxide ion, and (3) study the reactions of diethyl chloromalonate with phenoxide and ethoxide ions.","abstract_has_math":false,"creators":["Pulickal, Marietta C.H.F."],"institution":"Creighton University","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":[],"advisors":["Takemura, Kaz H."],"committee_chairs":[],"committee_members":[],"year":1968,"date_issued":"1968","date_published":"1968","updated_at":"2026-07-24T01:52:13Z","subjects":[],"languages":["en_US"],"rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"rights_urls":[],"identifier_entries":[]},"links":{"outbound_url":"http://hdl.handle.net/10504/111775","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Takemura, Kaz H."]},{"key":"dc:creator","label":"Author","values":["Pulickal, Marietta C.H.F."]}]},{"id":"academic_context","label":"Academic Context","entries":[{"key":"dc:date.accessioned","label":"Dc Date Accessioned","values":["2017-04-17T20:58:28Z"]},{"key":"dc:date.available","label":"Dc Date Available","values":["2017-04-17T20:58:28Z"]},{"key":"dc:date.issued","label":"Date","values":["1968"]},{"key":"dc:publisher","label":"Institution","values":["Creighton University"]},{"key":"dc:type","label":"Dc Type","values":["Thesis"]}]},{"id":"language_rights","label":"Language and Rights","entries":[{"key":"dc:language.iso","label":"Language (ISO)","values":["en_US"]},{"key":"dc:rights","label":"Dc Rights","values":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."]}]},{"id":"identifiers","label":"Identifiers","entries":[{"key":"dc:identifier.uri","label":"Identifier URI","values":["http://hdl.handle.net/10504/111775"]}]},{"id":"additional","label":"Additional Metadata","entries":[{"key":"dc:description.abstract","label":"Abstract","values":["In 1940, Niederi and Roth reported that both the diethyl monophenoxy- and diphenoxymalonates were formed in the reaction of diethyl bromomalonate with sodium phenoxide. The reaction has been investigated in an attempt to establish its mechanism. The purpose of this study was to (1) further examine the reaction of diethyl bromomalonate and sodium phenoxide, (2) investigate the behavior of the bromo- ester toward ethoxide ion, and (3) study the reactions of diethyl chloromalonate with phenoxide and ethoxide ions."]},{"key":"dc:title","label":"Title","values":["The Reactions of Diethyl Bromo- and Chloromalonates with Phenoxide and Ethoxide Ions"]}]}],"canonical_facts":{"dc:contributor.advisor":["Takemura, Kaz H."],"dc:creator":["Pulickal, Marietta C.H.F."],"dc:date.accessioned":["2017-04-17T20:58:28Z"],"dc:date.available":["2017-04-17T20:58:28Z"],"dc:date.issued":["1968"],"dc:description.abstract":["In 1940, Niederi and Roth reported that both the diethyl monophenoxy- and diphenoxymalonates were formed in the reaction of diethyl bromomalonate with sodium phenoxide. The reaction has been investigated in an attempt to establish its mechanism. The purpose of this study was to (1) further examine the reaction of diethyl bromomalonate and sodium phenoxide, (2) investigate the behavior of the bromo- ester toward ethoxide ion, and (3) study the reactions of diethyl chloromalonate with phenoxide and ethoxide ions."],"dc:identifier.uri":["http://hdl.handle.net/10504/111775"],"dc:language.iso":["en_US"],"dc:publisher":["Creighton University"],"dc:rights":["A non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above."],"dc:title":["The Reactions of Diethyl Bromo- and Chloromalonates with Phenoxide and Ethoxide Ions"],"dc:type":["Thesis"]},"updated_at":"2026-07-24T01:52:13Z"}