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Publikationsserver der RWTH Aachen University
Enantioselektive Pi-Komplexierung durch intramolekulare Chiralitätsübertragung aus CpTi-Aminosäure-Komplexen
Abstract
dc:descriptionThis work contains new synthesis of chiral CpTiL*-complexes where L* = amino acid, lactic acid or phenylethylamine. With these complexes the possibility for the preparation of enantiomerically enriched "titanocenes" [CpCppcTiCl2], where Cppc is a prochiral cyclopentadienide, was explored. In cyclopentadienylation L* acts as a chiral auxiliary ligand in an intramolecular chirality transfer. In the course of this work a new synthesis of Cppc has been developped.
Degree
thesis:*- Grantor dc:publisher
- Publikationsserver der RWTH Aachen University
- Year dc:date
- 2002
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Shin, Ueon-Sang
- Contributors dc:contributor
-
- Kölle, Ulrich
Subjects
dc:subject × 2Rights
dc:rights- Statement dc:rights
-
- info:eu-repo/semantics/openAccess
- Language dc:language
- ger
Identifiers
dc:identifier.*- OAI identifier oai:identifier
- oai:publications.rwth-aachen.de:56928