{"id":{"repo_id":"aachen","oai_identifier":"oai:publications.rwth-aachen.de:56928"},"canonical_url":"https://search.dev.ndltd.org/etd/aachen/oai:publications.rwth-aachen.de:56928","repository":{"repo_id":"aachen","name":"RWTH Aachen University","base_url":"https://publications.rwth-aachen.de/oai2d"},"display":{"title":"Enantioselektive Pi-Komplexierung durch intramolekulare Chiralitätsübertragung aus CpTi-Aminosäure-Komplexen","abstract":"This work contains new synthesis of chiral CpTiL*-complexes where L* = amino acid, lactic acid or phenylethylamine. With these complexes the possibility for the preparation of enantiomerically enriched \"titanocenes\" [CpCppcTiCl2], where Cppc is a prochiral cyclopentadienide, was explored. In cyclopentadienylation L* acts as a chiral auxiliary ligand in an intramolecular chirality transfer. 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With these complexes the possibility for the preparation of enantiomerically enriched \"titanocenes\" [CpCppcTiCl2], where Cppc is a prochiral cyclopentadienide, was explored. In cyclopentadienylation L* acts as a chiral auxiliary ligand in an intramolecular chirality transfer. In the course of this work a new synthesis of Cppc has been developped."]},{"key":"dc:source","label":"Dc Source","values":["Aachen : Publikationsserver der RWTH Aachen University IV, 104 S. : Ill. (2002). = Aachen, Techn. Hochsch., Diss., 2002"]},{"key":"dc:title","label":"Title","values":["Enantioselektive Pi-Komplexierung durch intramolekulare Chiralitätsübertragung aus CpTi-Aminosäure-Komplexen"]}]}],"canonical_facts":{"dc:contributor":["Kölle, Ulrich"],"dc:coverage":["DE"],"dc:creator":["Shin, Ueon-Sang"],"dc:date":["2002"],"dc:description":["This work contains new synthesis of chiral CpTiL*-complexes where L* = amino acid, lactic acid or phenylethylamine. With these complexes the possibility for the preparation of enantiomerically enriched \"titanocenes\" [CpCppcTiCl2], where Cppc is a prochiral cyclopentadienide, was explored. In cyclopentadienylation L* acts as a chiral auxiliary ligand in an intramolecular chirality transfer. In the course of this work a new synthesis of Cppc has been developped."],"dc:identifier":["https://publications.rwth-aachen.de/record/56928","https://publications.rwth-aachen.de/search?p=id:%22RWTH-CONV-119003%22"],"dc:language":["ger"],"dc:publisher":["Publikationsserver der RWTH Aachen University"],"dc:relation":["info:eu-repo/semantics/altIdentifier/urn/urn:nbn:de:hbz:82-opus-3460"],"dc:rights":["info:eu-repo/semantics/openAccess"],"dc:source":["Aachen : Publikationsserver der RWTH Aachen University IV, 104 S. : Ill. (2002). = Aachen, Techn. 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