Enantioselektive Pi-Komplexierung durch intramolekulare Chiralitätsübertragung aus CpTi-Aminosäure-Komplexen
type: CreativeWork
description: This work contains new synthesis of chiral CpTiL*-complexes where L* = amino acid, lactic acid or phenylethylamine. With these complexes the possibility for the preparation of enantiomerically enriched "titanocenes" [CpCppcTiCl2], where Cppc is a prochiral cyclopentadienide, was explored. In cyclopentadienylation L* acts as a chiral auxiliary ligand in an intramolecular chirality transfer. In the course of this work a new synthesis of Cppc has been developped.
abstract: This work contains new synthesis of chiral CpTiL*-complexes where L* = amino acid, lactic acid or phenylethylamine. With these complexes the possibility for the preparation of enantiomerically enriched "titanocenes" [CpCppcTiCl2], where Cppc is a prochiral cyclopentadienide, was explored. In cyclopentadienylation L* acts as a chiral auxiliary ligand in an intramolecular chirality transfer. In the course of this work a new synthesis of Cppc has been developped.
author: Shin, Ueon-Sang
language: ger
keywords: info:eu-repo/classification/ddc/540, Chemie
date published: 2002
date modified: 2026-07-30T19:42:01Z
provider: RWTH Aachen University
publisher: Networked Digital Library of Theses and Dissertations
type: WebPage
source organization: Publikationsserver der RWTH Aachen University