The characterization and chemistry of {\it mono\/}- and {\it bis\/}-cyclopentadienyl titanium thiolates.

The reactions of Cp$\rm\sb2TiCl\sb2$ with the dithiols, HS(CH$\sb2)\sb{\rm n}$SH (n = 2, 3) in the presence of imidazole proceed with formation of imidazole$\cdot$HCl affording relatively insoluble titanocene dithiolate derivatives 2.1 and 2.2 respectively. Alternatively, 2.2 can be prepared by the reaction of Cp$\rm\sb2TiPh\sb2$ with dithiol. The spectroscopic and analytical data are consistent with the formulation of 2.1 and 2.2 as the bimetallic compounds Cp\rm\sb2Ti(μ-S(CH$\sb2)\sb{\rm n}\rm S)\sb2TiCp\sb2$ (n = 2 2.1, n = 3 2.2). Source: Dissertation Abstracts International, Volume: 55-05, Section: B, page: 1842. Adviser: D. W. Stephan. Thesis (Ph.D.)--University of Windsor (Canada), 1993.

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Doctoral

Discipline thesis:degree_discipline

Chemistry and Biochemistry

Grantor

University of Windsor

Year dc:date.issued

1993

Author dc:creator

• Nadasdi, Todd Timothy.

Advisor dc:contributor.advisor

• Stephan, D. W.,

Licence

• http://creativecommons.org/licenses/by-nc-nd/4.0/

Language dc:language.iso

en_CA

Handle dc:identifier.uri

https://hdl.handle.net/20.500.14776/3410

OAI identifier oai:identifier

oai:uwindsor.scholaris.ca:20.500.14776/3410