{"id":{"repo_id":"windsor","oai_identifier":"oai:uwindsor.scholaris.ca:20.500.14776/3410"},"canonical_url":"https://search.dev.ndltd.org/etd/windsor/oai:uwindsor.scholaris.ca:20.500.14776/3410","repository":{"repo_id":"windsor","name":"University of Windsor","base_url":"https://uwindsor.scholaris.ca/server/oai/request"},"display":{"title":"The characterization and chemistry of {\\it mono\\/}- and {\\it bis\\/}-cyclopentadienyl titanium thiolates.","abstract":"The reactions of Cp$\\rm\\sb2TiCl\\sb2$ with the dithiols, HS(CH$\\sb2)\\sb{\\rm n}$SH (n = 2, 3) in the presence of imidazole proceed with formation of imidazole$\\cdot$HCl affording relatively insoluble titanocene dithiolate derivatives 2.1 and 2.2 respectively. Alternatively, 2.2 can be prepared by the reaction of Cp$\\rm\\sb2TiPh\\sb2$ with dithiol. The spectroscopic and analytical data are consistent with the formulation of 2.1 and 2.2 as the bimetallic compounds Cp$\\rm\\sb2Ti(\\mu$-S(CH$\\sb2)\\sb{\\rm n}\\rm S)\\sb2TiCp\\sb2$ (n = 2 2.1, n = 3 2.2). Source: Dissertation Abstracts International, Volume: 55-05, Section: B, page: 1842. Adviser: D. W. Stephan. Thesis (Ph.D.)--University of Windsor (Canada), 1993.","abstract_html":"The reactions of Cp$\\rm\\sb2TiCl\\sb2$ with the dithiols, HS(CH$\\sb2)\\sb{\\rm n}$SH (n = 2, 3) in the presence of imidazole proceed with formation of imidazole$\\cdot$HCl affording relatively insoluble titanocene dithiolate derivatives 2.1 and 2.2 respectively. Alternatively, 2.2 can be prepared by the reaction of Cp$\\rm\\sb2TiPh\\sb2$ with dithiol. The spectroscopic and analytical data are consistent with the formulation of 2.1 and 2.2 as the bimetallic compounds Cp<span class=\"etd-inline-math\">\\rm\\sb2Ti(&mu;</span>-S(CH$\\sb2)\\sb{\\rm n}\\rm S)\\sb2TiCp\\sb2$ (n = 2 2.1, n = 3 2.2). Source: Dissertation Abstracts International, Volume: 55-05, Section: B, page: 1842. Adviser: D. W. Stephan. Thesis (Ph.D.)--University of Windsor (Canada), 1993.","abstract_has_math":true,"creators":["Nadasdi, Todd Timothy."],"institution":"University of Windsor","degree_name":"Ph.D.","degree_level":"Doctoral","degree_discipline":"Chemistry and Biochemistry","degree_department":null,"school":null,"contributors":[],"advisors":["Stephan, D. W.,"],"committee_chairs":[],"committee_members":[],"year":1993,"date_issued":"1993-01-01","date_published":"1993-01-01","updated_at":"2026-07-27T22:04:46Z","subjects":[],"languages":["en_CA"],"rights":[],"rights_urls":["http://creativecommons.org/licenses/by-nc-nd/4.0/"],"identifier_entries":[]},"links":{"outbound_url":"https://hdl.handle.net/20.500.14776/3410","outbound_label":"Handle","outbound_source":"dc:identifier.uri"},"metadata_groups":[{"id":"people","label":"People","entries":[{"key":"dc:contributor.advisor","label":"Advisor","values":["Stephan, D. 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Alternatively, 2.2 can be prepared by the reaction of Cp$\\rm\\sb2TiPh\\sb2$ with dithiol. The spectroscopic and analytical data are consistent with the formulation of 2.1 and 2.2 as the bimetallic compounds Cp$\\rm\\sb2Ti(\\mu$-S(CH$\\sb2)\\sb{\\rm n}\\rm S)\\sb2TiCp\\sb2$ (n = 2 2.1, n = 3 2.2). Source: Dissertation Abstracts International, Volume: 55-05, Section: B, page: 1842. Adviser: D. W. Stephan. Thesis (Ph.D.)--University of Windsor (Canada), 1993."]},{"key":"dc:title","label":"Title","values":["The characterization and chemistry of {\\it mono\\/}- and {\\it bis\\/}-cyclopentadienyl titanium thiolates."]}]}],"canonical_facts":{"dc:contributor.advisor":["Stephan, D. W.,"],"dc:creator":["Nadasdi, Todd Timothy."],"dc:date.accessioned":["2025-06-20 10:49"],"dc:date.available":["2013-03-22 15:06","2025-06-20T14:49:40Z"],"dc:date.issued":["1993-01-01"],"dc:description.abstract":["The reactions of Cp$\\rm\\sb2TiCl\\sb2$ with the dithiols, HS(CH$\\sb2)\\sb{\\rm n}$SH (n = 2, 3) in the presence of imidazole proceed with formation of imidazole$\\cdot$HCl affording relatively insoluble titanocene dithiolate derivatives 2.1 and 2.2 respectively. Alternatively, 2.2 can be prepared by the reaction of Cp$\\rm\\sb2TiPh\\sb2$ with dithiol. The spectroscopic and analytical data are consistent with the formulation of 2.1 and 2.2 as the bimetallic compounds Cp$\\rm\\sb2Ti(\\mu$-S(CH$\\sb2)\\sb{\\rm n}\\rm S)\\sb2TiCp\\sb2$ (n = 2 2.1, n = 3 2.2). Source: Dissertation Abstracts International, Volume: 55-05, Section: B, page: 1842. Adviser: D. W. Stephan. Thesis (Ph.D.)--University of Windsor (Canada), 1993."],"dc:identifier.uri":["https://hdl.handle.net/20.500.14776/3410"],"dc:language.iso":["en_CA"],"dc:rights":["http://creativecommons.org/licenses/by-nc-nd/4.0/"],"dc:title":["The characterization and chemistry of {\\it mono\\/}- and {\\it bis\\/}-cyclopentadienyl titanium thiolates."],"dc:type":["info:eu-repo/semantics/doctoralThesis"],"thesis:degree_discipline":["Chemistry and Biochemistry"],"thesis:degree_level":["Doctoral"],"thesis:degree_name":["Ph.D."],"thesis:institution_name":["University of Windsor"]},"updated_at":"2026-07-27T22:04:46Z"}