Nanocomposite Dispersion: Quantifying the Structure-Function Relationship

The dispersion quality of nanoinclusions within a matrix material is often overlooked when relating the effect of nanoscale structures on functional performance and processing/property relationships for nanocomposite materials. This is due in part to the difficulty in visualizing the nanoinclusion and ambiguity in the description of dispersion. Understanding the relationships between the composition of the nanofiller, matrix chemistry, processing procedures and resulting dispersion is a necessary step to tailor the physical properties. A method is presented that incorporates high-contrast imaging, an emerging scanning electron microscopy technique to visualize conductive nanofillers deep within insulating materials, with various image processing procedures to allow for the quantification and validation of dispersion parameters. This method makes it possible to quantify the dispersion of various single wall carbon nanotube (SWCNT)-polymer composites as a function of processing conditions, composition of SWCNT and polymer matrix chemistry. Furthermore, the methodology is utilized to show that SWCNT dispersion exhibits fractal-like behavior thus allowing for simplified quantitative dispersion analysis. The dispersion analysis methodology will be corroborated through comparison to results from small angle neutron scattering dispersion analysis. Additionally, the material property improvement of SWCNT nanocomposites are linked to the dispersion state of the nanostructure allowing for correlation between dispersion techniques, quantified dispersion of SWCNT at the microscopic scale and the material properties measured at the macroscopic scale.

Name thesis:degree_name

Ph. D.

Level thesis:degree_level

doctoral

Discipline thesis:degree_discipline

Materials Science and Engineering

Department dc:contributor.department

Materials Science and Engineering

Grantor dc:publisher

Virginia Tech

Year dc:date.issued

2011

Author dc:creator

• Gibbons, Luke J.

Chair dc:contributor.committeechair

• Leo, Donald J.

Committee members dc:contributor.committeemember

• Lillehei, Peter T.
• Priya, Shashank
• Logan, Kathryn V.
• Park, Cheol

• Nanocomposite dispersion
• High-contrast scanning electron microscopy
• Single wall carbon nanotube
• Nanotube dispersion quantification

Statement dc:rights

• In Copyright

Licence dc:rights.uri

• http://rightsstatements.org/vocab/InC/1.0/

Language dc:language.iso

en_US

Dc Identifier Other

etd-09202011-144433

OAI identifier oai:identifier

oai:vtechworks.lib.vt.edu:10919/77214