Abstract
dc:description.abstractAn improved knowledge of wood material behavior in hot-pressing environments can provide the benefit of an increased understanding of material properties during the manufacture of wood-based composites as well as insight into the development of new processes and products which manipulate the viscoelastic nature of wood. Two specific areas where additional knowledge is needed are: the high temperature equilibrium moisture content (EMC) behavior and the moisture dependent softening behavior. EMC data was collected and desorption isotherms were generated for mature and juvenile wood of aspen, loblolly pine and yellow-poplar at 50 and 160°C. High temperature EMC behavior was found to be distinct from that at lower temperatures, and considerable differences between the isotherms for juvenile and mature wood were detected. Substantial thermal degradation was observed during desorption at 160 °C and found to be strongly influenced by relative humidity. The thermal softening behavior of wood was evaluated using dielectric thermal analysis (DETA) at moisture levels from 0 to 20 percent. Coincident in situ relaxations of hemicellulose and amorphous cellulose in the range of 20 to 200 °C were observed and found to exhibit the characteristics of a secondary (glass) transition. The moisture dependence of this transition was characterized, and differences in the observed Tg were detected between juvenile and mature wood. Time-temperature superposition was also shown to be applicable to the wood-water system.
Degree
thesis:*- Name thesis:degree_name
- Ph. D.
- Level thesis:degree_level
- doctoral
- Discipline thesis:degree_discipline
- Wood Science and Forest Products
- Department dc:contributor.department
- Wood Science and Forest Products
- Grantor dc:publisher
- Virginia Tech
- Year dc:date.issued
- 1999
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Lenth, Christopher Allen
- Chair dc:contributor.committeechair
-
- Kamke, Frederick A.
- Committee members dc:contributor.committeemember
-
- Watson, Layne T.
- Loferski, Joseph R.
- Dillard, David A.
- Zink-Sharp, Audrey G.
- Frazier, Charles E.
Subjects
dc:subject × 4Rights
dc:rights- Statement dc:rights
-
- In Copyright
- Licence dc:rights.uri
Identifiers
dc:identifier.*- Dc Identifier Other
- etd-08302000-12360026
- OAI identifier oai:identifier
- oai:vtechworks.lib.vt.edu:10919/28826