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Virginia Tech

Surface Modification Of Exhausted Activated Carbon For The Enhanced Removal Of Per- And Polyfluoroalkyl Substances

Abstract

dc:description.abstractgeneral

Granular activated carbon (GAC) is a treatment technology commonly used in drinking water treatment. Recently, a maximum contaminant limit (MCL) has been proposed for a group of per- and polyfluoroalkyl substances (PFAS), a class of chemicals that have been used in many consumer products and industrial applications. GAC is capable of the treatment of PFAS below the MCL, but in many water sources competing contaminants are present that are also removed by GAC, reducing the capacity for PFAS removal. This requires more frequent replacement of the carbon media and greatly increases the cost of the treatment. Surface modification can be performed to increase the removal capacity and specificity of the GAC, allowing more of its removal capacity to be used for PFAS. Surface modification is performed by coating the GAC in a chemical that is then immobilized on the carbon through electrostatic and hydrophobic interactions. As GAC and many micropollutants treated by GAC, including the regulated PFAS, are negative, performing surface modification using a positive chemical increases the removal capacity of the carbon. Bench-scale tests using fully exhausted carbon showed PFAS removal following up-flow and influent addition surface modification.

Degree

thesis:*
Name thesis:degree_name
Master of Science
Level thesis:degree_level
masters
Discipline thesis:degree_discipline
Environmental Engineering
Department dc:contributor.department
Environmental Science and Engineering
Grantor dc:publisher
Virginia Tech
Year dc:date.issued
2025

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Waller, Christopher Alan Jr.
Chairs dc:contributor.committeechair
  • Widdowson, Mark A.
  • Bott, Charles B.
Committee member dc:contributor.committeemember
  • Edwards, Marc A.

Subjects

dc:subject × 4

Rights

dc:rights
Statement dc:rights
  • In Copyright
Language dc:language.iso
en

Identifiers

dc:identifier.*
Dc Identifier Other
vt_gsexam:41854
OAI identifier oai:identifier
oai:vtechworks.lib.vt.edu:10919/124083

Chain of custody

source
Harvested from
Virginia Tech
Base URL
vtechworks.lib.vt.edu/oai/request
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Waller, Christopher Alan Jr.. Surface Modification Of Exhausted Activated Carbon For The Enhanced Removal Of Per- And Polyfluoroalkyl Substances. masters thesis, Virginia Tech, 2025. https://hdl.handle.net/10919/124083