NMR Study of n-Propyllithium Aggregates

A variable temperature 1H, 13C, and 6Li NMR study of n-propyl-6Li-lithium showed five different aggregates, similar to that in the literature as (RLi)n, n= 6, 8, 9, 9, 9. There were also a number of additional new species, identified as lithium hydride containing aggregates. Unexpectedly, a series of 13C{1H} 1-D NMR experiments with selective 6Li decoupling showed evidence for 13C-6Li spin-spin coupling between the previously reported (RLi)n aggregates and various hydride species.

Grantor dc:publisher

University of North Texas

Year dc:date

2002

Author dc:creator

• Davis, James W.

Contributors dc:contributor

• Thomas, Ruthanne D.
• Richmond, Michael

• Hydrides.
• Organolithium compounds.
• lithium aggregates
• Hydrides
• aklyllithium
• NMR

Statement dc:rights

• Public
• Copyright
• Davis, James W.
• Copyright is held by the author, unless otherwise noted. All rights reserved.

Language dc:language

English

Identifier

oclc: 54494273
https://digital.library.unt.edu/ark:/67531/metadc3350/
ark: ark:/67531/metadc3350

OAI identifier oai:identifier

info:ark/67531/metadc3350