{"id":{"repo_id":"unt","oai_identifier":"info:ark/67531/metadc3350"},"canonical_url":"https://search.dev.ndltd.org/etd/unt/info:ark/67531/metadc3350","repository":{"repo_id":"unt","name":"University of North Texas","base_url":"https://digital.library.unt.edu/oai/"},"display":{"title":"NMR Study of n-Propyllithium Aggregates","abstract":"A variable temperature 1H, 13C, and 6Li NMR study of n-propyl-6Li-lithium showed five different aggregates, similar to that in the literature as (RLi)n, n= 6, 8, 9, 9, 9. There were also a number of additional new species, identified as lithium hydride containing aggregates. Unexpectedly, a series of 13C{1H} 1-D NMR experiments with selective 6Li decoupling showed evidence for 13C-6Li spin-spin coupling between the previously reported (RLi)n aggregates and various hydride species.","abstract_html":"A variable temperature 1H, 13C, and 6Li NMR study of n-propyl-6Li-lithium showed five different aggregates, similar to that in the literature as (RLi)n, n= 6, 8, 9, 9, 9. There were also a number of additional new species, identified as lithium hydride containing aggregates. Unexpectedly, a series of 13C{1H} 1-D NMR experiments with selective 6Li decoupling showed evidence for 13C-6Li spin-spin coupling between the previously reported (RLi)n aggregates and various hydride species.","abstract_has_math":false,"creators":["Davis, James W."],"institution":"University of North Texas","degree_name":null,"degree_level":null,"degree_discipline":null,"degree_department":null,"school":null,"contributors":["Thomas, Ruthanne D.","Richmond, Michael"],"advisors":[],"committee_chairs":[],"committee_members":[],"year":2002,"date_issued":"2002-12","date_published":"2002-12","updated_at":"2026-07-24T05:34:52Z","subjects":["Hydrides.","Organolithium compounds.","lithium aggregates","Hydrides","aklyllithium","NMR"],"languages":["English"],"rights":["Public","Copyright","Davis, James W.","Copyright is held by the author, unless otherwise noted. 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Unexpectedly, a series of 13C{1H} 1-D NMR experiments with selective 6Li decoupling showed evidence for 13C-6Li spin-spin coupling between the previously reported (RLi)n aggregates and various hydride species."]},{"key":"dc:format","label":"Dc Format","values":["Text"]},{"key":"dc:title","label":"Title","values":["NMR Study of n-Propyllithium Aggregates"]}]}],"canonical_facts":{"dc:contributor":["Thomas, Ruthanne D.","Richmond, Michael"],"dc:creator":["Davis, James W."],"dc:date":["2002-12"],"dc:description":["A variable temperature 1H, 13C, and 6Li NMR study of n-propyl-6Li-lithium showed five different aggregates, similar to that in the literature as (RLi)n, n= 6, 8, 9, 9, 9. There were also a number of additional new species, identified as lithium hydride containing aggregates. Unexpectedly, a series of 13C{1H} 1-D NMR experiments with selective 6Li decoupling showed evidence for 13C-6Li spin-spin coupling between the previously reported (RLi)n aggregates and various hydride species."],"dc:format":["Text"],"dc:identifier":["oclc: 54494273","doi: 10.12794/metadc3350","https://digital.library.unt.edu/ark:/67531/metadc3350/","ark: ark:/67531/metadc3350"],"dc:language":["English"],"dc:publisher":["University of North Texas"],"dc:rights":["Public","Copyright","Davis, James W.","Copyright is held by the author, unless otherwise noted. All rights reserved."],"dc:subject":["Hydrides.","Organolithium compounds.","lithium aggregates","Hydrides","aklyllithium","NMR"],"dc:title":["NMR Study of n-Propyllithium Aggregates"],"dc:type":["Thesis or Dissertation"]},"updated_at":"2026-07-24T05:34:52Z"}