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University of Illinois at Urbana-Champaign
Ketone -Catalyzed Epoxidation of Alkenes With Oxone and Palladium -Catalyzed Biaryl Synthesis via Silacyclobutanes
Abstract
dc:descriptionAryl(fluoro)silacyclobutanes and aryl(chloro)silacyclobutanes have been found to undergo cross-coupling reactions with aryl iodides. The rate of reaction and extent of homocoupling were dramatically affected by the addition of ligands for the palladium catalyst. A wide range of electronically different and structurally diverse unsymmetrical biaryls have been prepared in good to excellent yields.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Wu, Zhicai
- Contributors dc:contributor
-
- Denmark, Scott E.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9955682
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84470