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University of Illinois at Urbana-Champaign
Studies in Asymmetric Catalysis. Part I. Lewis Base-Catalyzed Aldol Additions. Part II. Bis(oxazoline)palladium(ii)-Catalyzed Cyclopropanation
Abstract
dc:descriptionA variety of bis(oxazoline)palladium(II) complexes were prepared and tested in the cyclopropanation of ethyl (E)-cinnamate with diazomethane. Although an enantioselective process was never realized, effects of substitution on the ligand, catalyst loading studies, and other investigations led to a mechanistic proposal wherein partial or complete ligand dissociation occurs (depending on the ligand structure) during the course of the cyclopropanation event.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Stavenger, Robert Allen
- Contributors dc:contributor
-
- Denmark, Scott E.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9921737
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84438