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University of Illinois at Urbana-Champaign
Investigations of Chemiluminescence Detection Parameters for Kinetic Analysis and Capillary Separations
Abstract
dc:descriptionA post-column CL detection method for capillary electrophoresis (CE) was developed in which the capillary effluent was collected on a membrane which had been coated with bis(2,4,6-trichlorophenyl)oxalate, a CL reagent. After the CE run, the CL reaction was initiated on the membrane by applying hydrogen peroxide, a scientific CCD camera imaged the resultant CL emission, and an electropherogram was reconstructed. This post-column detection scheme decouples the separation parameters from detection and allows longer lived CL reagents to be used with fast separations.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Shultz, Loranelle Louise
- Contributors dc:contributor
-
- Nieman, T.A.
- Sweedler, J.V.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI9812772
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84392