Back to results
University of Illinois at Urbana-Champaign
Organoosmium(IV) Hydroxo Complexes and the Synthesis of Heterobimetallic Catalysts for Aerobic Alcohol Oxidation
Abstract
dc:descriptionChapter 4. The compounds dibenzoylmethane and N-phenylsalicylaldimine react with VOCl3 in toluene to generate complex V(O)Cl2(dbm) (dbm =C6H5C(O)CHC(O)C 6H5) and a complex of the empirical formula C13H 11Cl3NO2V. The square pyramidal complex V(O)Cl 2(dbm) is a black solid that is stable in solution, but reacts with trace water. The complex C13H11Cl3NO 2V is unstable in solution. In a solution of ether/hexane, V(O)Cl 2(dbm) reacts with NaOSiMe3 to yield the uncharacterized intermediate V(O)(dbm)(OSiMe3)2, which reacts with the organometallic dihydroxo complex [N(n-Bu)4][ cis-Os(N)(CH2SiMe3)2(OH)2] to generate Os(N)(CH2SiMe3)2(dbm).
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Kiefer, Adam
- Contributors dc:contributor
-
- Shapley, Patricia A.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI3337817
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84313