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University of Illinois at Urbana-Champaign
I. Efforts Toward the Total Synthesis of the Stemofoline Alkaloids II. Preliminary Development of a Method to Prepare 1,2-Cis-2-Acetamido-2-Deoxyglycopyranoses
Abstract
dc:descriptionEfforts to prepare the stemofoline alkaloids via total synthesis are described. Each strategy which is presented utilized a [3+2] cycloaddition of a non-stabilized azomethine ylide as a key step. These studies culminated in the first non-racemic synthesis of the fully-oxygenated tricyclic core of the stemofoline alkaloids. Furthermore, a novel synthetic method to prepare alpha-linked C2-acetamido glycoconjugates is described and preliminary results are presented.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Carra, Ryan
- Contributors dc:contributor
-
- Gin, David Y.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI3337716
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84303