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University of Illinois at Urbana-Champaign

Studies on the Silanol-Based Cross-Coupling Reaction: (1) Development of Methods for the Synthesis of Aryl and Heteroaryldimethysilanols, (2) Expansion of the Substrate Scope of the Cross-Coupling Reaction and (3) Investigations on the Transmetalation of Organosilanols to Transition Metals

Abstract

dc:description

To further illuminate the mechanism of transmetalation of alkenyldimethylsilanols a number of molecular traps have been designed, synthesized and subjected to the cross-coupling reaction. A clear preference for formation of the cross-coupling products was observed in these investigations.

Degree

thesis:*
Name thesis:degree_name
Ph.D.
Level thesis:degree_level
Dissertation
Discipline thesis:degree_discipline
Chemistry
Grantor
University of Illinois at Urbana-Champaign
Year dc:date
2015

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Kallemeyn, Jeffrey M.
Contributors dc:contributor
  • Denmark, Scott E.

Subjects

dc:subject × 1

Rights

Language dc:language
eng

Identifiers

dc:identifier.*
Identifier
(MiAaPQ)AAI3269934
OAI identifier oai:identifier
oai:www.ideals.illinois.edu:2142/84259

Chain of custody

source
Harvested from
University of Illinois - Urbana-Champaign
Base URL
www.ideals.illinois.edu/oai-pmh
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Kallemeyn, Jeffrey M.. Studies on the Silanol-Based Cross-Coupling Reaction: (1) Development of Methods for the Synthesis of Aryl and Heteroaryldimethysilanols, (2) Expansion of the Substrate Scope of the Cross-Coupling Reaction and (3) Investigations on the Transmetalation of Organosilanols to Transition Metals. Dissertation thesis, University of Illinois at Urbana-Champaign, 2015. http://hdl.handle.net/2142/84259