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University of Illinois at Urbana-Champaign
Synthesis and Maldi-Ms Characterization of New Ruthenium Sulfide Clusters
Abstract
dc:descriptionFinally, ruthenium sulfide phosphine nitrosyl clusters resulting from the reaction of RuCl3(NO)(P(aryl)3)2 and S(TMS)2 were investigated. The distorted heterocubane Ru4 S4(NO)4(PPh3)3 was crystallographically characterized and a related cluster with formula Ru4S3(NO) 4(PPh3)3, possibly corresponding to a partial heterocubane structure, was identified using MALDI-MS and IR spectroscopy.
Degree
thesis:*- Name thesis:degree_name
- Ph.D.
- Level thesis:degree_level
- Dissertation
- Discipline thesis:degree_discipline
- Chemistry
- Grantor
- University of Illinois at Urbana-Champaign
- Year dc:date
- 2015
Author and committee
dc:creator, dc:contributor.*- Author dc:creator
-
- Eckermann, Amanda Lorraine
- Contributors dc:contributor
-
- Rauchfuss, Thomas B.
Subjects
dc:subject × 1Rights
- Language dc:language
- eng
Identifiers
dc:identifier.*- Identifier
- (MiAaPQ)AAI3069989
- OAI identifier oai:identifier
- oai:www.ideals.illinois.edu:2142/84067