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University of Illinois at Urbana-Champaign

Reaction of Aqueous Polyoxometalates With Silver and Gold Surfaces

Abstract

dc:description

Preliminary experiments to study the reaction of acidic aqueous solutions of the Preyssler anion, NaP5W30O110 14-, with Ag(111) show that a surface phase is formed. Immersion of Au(111) in the same solutions yielded STM images that did not show evidence of a surface phase. By using a mixture of alpha-PVW11O40 4- and NaP5W30O110 14- in acidic aqueous solution, the terrace size of the surface phase formed on Ag(111) increased and its translational order improved.

Degree

thesis:*
Name thesis:degree_name
Ph.D.
Level thesis:degree_level
Dissertation
Discipline thesis:degree_discipline
Chemistry
Grantor
University of Illinois at Urbana-Champaign
Year dc:date
2015

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Powell, Jason Daniel
Contributors dc:contributor
  • Klemperer, Walter G.

Subjects

dc:subject × 1

Rights

Language dc:language
eng

Identifiers

dc:identifier.*
Identifier
(MiAaPQ)AAI3023174
OAI identifier oai:identifier
oai:www.ideals.illinois.edu:2142/84050

Chain of custody

source
Harvested from
University of Illinois - Urbana-Champaign
Base URL
www.ideals.illinois.edu/oai-pmh
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Powell, Jason Daniel. Reaction of Aqueous Polyoxometalates With Silver and Gold Surfaces. Dissertation thesis, University of Illinois at Urbana-Champaign, 2015. http://hdl.handle.net/2142/84050