Back to results

University of Illinois at Urbana-Champaign

Polyoxoniobates: How Solution Chemistry Helps to Understand the Solid State

Abstract

dc:description

A structural model is proposed for the chemical B-site ordering in relaxor ferroelectric Pb3ZnNb2O9 and Pb3MgNb 2O9. The basis for this model is the imposition of order using a divalent cation nearest-neighbor exclusion algorithm on a random cubic lattice with 2:1 Nb:(Mg/Zn) occupancy. The ordered structure obtained is consistent with current structural data obtained on these compounds.

Degree

thesis:*
Name thesis:degree_name
Ph.D.
Level thesis:degree_level
Dissertation
Discipline thesis:degree_discipline
Chemistry
Grantor
University of Illinois at Urbana-Champaign
Year dc:date
2015

Author and committee

dc:creator, dc:contributor.*
Author dc:creator
  • Marek, Keith Adam
Contributors dc:contributor
  • Klemperer, Walter G.

Subjects

dc:subject × 1

Rights

Language dc:language
eng

Identifiers

dc:identifier.*
Identifier
(MiAaPQ)AAI3023134
OAI identifier oai:identifier
oai:www.ideals.illinois.edu:2142/84046

Chain of custody

source
Harvested from
University of Illinois - Urbana-Champaign
Base URL
www.ideals.illinois.edu/oai-pmh
Last updated
2026-07-22
Source record
OAI-PMH GetRecord
citation

Marek, Keith Adam. Polyoxoniobates: How Solution Chemistry Helps to Understand the Solid State. Dissertation thesis, University of Illinois at Urbana-Champaign, 2015. http://hdl.handle.net/2142/84046