Porphyrin Network Materials: Chemical Exploration in the Supramolecular Solid-State

The large internal cavities of PIZA-1 are a consequence of the trinuclear Co(II)carboxylate cluster forcing the ruffling of the porphyrin building blocks. The linear trinuclear metal-carboxylate cluster of PIZA-1 is contrasted with the bent trinuclear M(II) carboxylate clusters (M = Co, Mn) of isostructural 3-dimensional frameworks: PIZA-2 and PIZA-3. Containing near-planar metalloporphyrin macrocycles, PIZA-2 and PIZA-3 manifest lower void volumes (56%).

Name thesis:degree_name

Ph.D.

Level thesis:degree_level

Dissertation

Discipline thesis:degree_discipline

Chemistry

Grantor

University of Illinois at Urbana-Champaign

Year dc:date

2015

Author dc:creator

• Kosal, Margaret Elizabeth

Contributors dc:contributor

• Kenneth S. Suslick

• Engineering, Materials Science

Language dc:language

eng

Identifier

(MiAaPQ)AAI3023099

OAI identifier oai:identifier

oai:www.ideals.illinois.edu:2142/84043